Messanae Universitas Studiorum

Polarographic investigation on complex equilibria in Cd(II)-substituted thiourea halide system in aqueous solution

Lodyga Chruscinska, Elzbieta and De Marco, Domenico (1988) Polarographic investigation on complex equilibria in Cd(II)-substituted thiourea halide system in aqueous solution. Accademia Peloritana dei Pericolanti, Classe di Scienze FF. MM. NN., LXVI. pp. 391-397.

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    Abstract

    Two ligand mixed complex formation between Cd(II) and both Methylthiourea and Bromide has been investigated in water solution at = 25 °C and $LiClO_4$ 0.5 M by Polarography.
    Mixed constants for the reactions $i/m CdX_m + j/m CdY_m = CdX_iY_j$ (i + j = m. Charges are omitted) are always positive independently from the coordination level m.
    Coordinated ligand (ligands) negatively affects (affect) the affinity of the incoming ligand when this is the same in nature, but more favourable free energy changes are calculated when the coordinated ligand (Iigands) and the incoming one are different.

    Item Type: Article
    Subjects: M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Fisiche, Matematiche e Naturali > 1988
    M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Giuridiche, Economiche e Politiche > 1988
    M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Lettere, Filosofia e belle Arti > 1988
    Divisions: UNSPECIFIED
    Depositing User: Dr A F
    Date Deposited: 08 Oct 2012 10:45
    Last Modified: 22 Jan 2013 10:19
    URI: http://cab.unime.it/mus/id/eprint/1024

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