Messanae Universitas Studiorum

Cinetica termica della decomposizione di $CIS-E-TRANS-Fe(CNCH_3)_4(CN)_2$

De Marco, R. M. and Giuffrida, A. and Guglielmo, Giovanni and Romeo, Grazia (1980) Cinetica termica della decomposizione di $CIS-E-TRANS-Fe(CNCH_3)_4(CN)_2$. Accademia Peloritana dei Pericolanti - Classe di Scienze FF.MM.NN., LVIII (1). pp. 51-59.

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Abstract

Kinetic data for the reaction of thermal decomposition of cis- and trans -$Fe(CNCH_3)_4(CN)_2$ with $H^+$ or $Hg^2^+$ in aqueous solution at different temperatures are reported. A mechanism, involving a fast protonation or a formation of labile adduct in equilibrium with the substrates is proposed. This is followed by the paths of reaction controlled by the rate constant which refer to the decomposition of the isolated aquocomplex $Fe(CNCH_3)_4(CN)H_2O+$.

Item Type: Article
Subjects: M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Fisiche, Matematiche e Naturali > 1980
M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Medico-Biologiche > 1980
M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Giuridiche, Economiche e Politiche > 1980
M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Lettere, Filosofia e belle Arti > 1980
Depositing User: Dr PP C
Date Deposited: 08 Oct 2012 15:50
Last Modified: 22 Jan 2013 12:11
URI: http://cab.unime.it/mus/id/eprint/1088

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