Messanae Universitas Studiorum

Kinetics of the sulphoxide displacement in cis-disphenylbis (dimethyl-sulphoxido platinum (II) by 2,2'-bipyridine in the coordinating solvent acetonitrile

Lanza, Santo (1983) Kinetics of the sulphoxide displacement in cis-disphenylbis (dimethyl-sulphoxido platinum (II) by 2,2'-bipyridine in the coordinating solvent acetonitrile. Accademia Peloritana dei Pericolanti, Classe di Scienze FF. MM. NN., LXI. pp. 335-346.

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Abstract

A kinetic study has been undertaken of the reaction between cis $[Pt(C_6H_5)_2(Me_2SO)_2]$ and 2,2’-bipyridine in the coordinating solvent acetonitrile, where the starting material is in equilibrium with the solvento species cis-$[Pt(C_6H_5)_2(Me2SO)(CH_3CN)]$. The proposed reaction mechanism involves the dissociative loss of $Me_2SO$ and $CH_3CN$ respectively, assisted by the oxygen atom of the remaining sulphoxide.

Item Type: Article
Subjects: M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Fisiche, Matematiche e Naturali > 1983
M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Medico-Biologiche > 1983
M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Lettere, Filosofia e belle Arti > 1983
Depositing User: Dr A F
Date Deposited: 09 Oct 2012 08:31
Last Modified: 09 Oct 2012 08:31
URI: http://cab.unime.it/mus/id/eprint/1113

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