Messanae Universitas Studiorum

Studio della razione fra etere diallilico e $PdCL_4^2-$ in soluzioni metanolo-acquose

Pietropaolo, R. and Faraone, F. and Pietropaolo, D. and Sergi, S. (1971) Studio della razione fra etere diallilico e $PdCL_4^2-$ in soluzioni metanolo-acquose. Accademia Peloritana dei Pericolanti - Classe di Scienze FF.MM.NN., LI (1). pp. 231-238.

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    Abstract

    A Kinetic study of the reaction between $PdCl_4^2-$ and Allylaether is reported. The Kinetic law observed has the form:

    $K_o_s_s$ = $\frac {K[(CH_2=CHCH_2)_2O]}{[H^+][Cl^-]^2}$

    and is interpreted assuming that a nucleophilic attack of the £OH^-$ coordinated to the Palladium (II) on the coordinated olefinic double bond of the allylaether is the rate determining step. [math mode missing closing $]

    Item Type: Article
    Subjects: M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Fisiche, Matematiche e Naturali > 1971
    M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Medico-Biologiche > 1971
    Divisions: UNSPECIFIED
    Depositing User: Dr PP C
    Date Deposited: 08 Apr 2013 10:07
    Last Modified: 08 Apr 2013 10:07
    URI: http://cab.unime.it/mus/id/eprint/1396

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