Amati, L. and Magon, L. and Mazzocchin, G. A. and Portanova, R. (1973) Indagini polarografiche su complessi dello ione uranile (VI) in solventi non acquosi. Accademia Peloritana dei Pericolanti - Classe di Scienze FF.MM.NN., LIII (1). pp. 159-174.
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Abstract
The behaviour of uranyl ion in dimethylsulphoxide, dimethylformamide and acetonitrile has been investigated in the presence of $Cl^—$, $B^r—$, $I^-$ and $CH_3COO^-$ ligands.
The investigations were carried out at 25°C by polarography and oscillopolarography.
The experimental data allowed the determination of the ratio between the association constants of $U^V^I$ and $U^V$ complexes in DMS0 and DMF.
A relative stability sequence of the studied complexes as a function of the “Donor Number” and of "Dieletric Costant” of the solvent has been established.
| Item Type: | Article |
|---|---|
| Subjects: | M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Fisiche, Matematiche e Naturali > 1973 |
| Depositing User: | Dr PP C |
| Date Deposited: | 24 Oct 2012 10:29 |
| Last Modified: | 24 Oct 2012 10:29 |
| URI: | http://cab.unime.it/mus/id/eprint/1413 |
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