Messanae Universitas Studiorum

Indagini polarografiche su complessi dello ione uranile (VI) in solventi non acquosi

Amati, L. and Magon, L. and Mazzocchin, G. A. and Portanova, R. (1973) Indagini polarografiche su complessi dello ione uranile (VI) in solventi non acquosi. Accademia Peloritana dei Pericolanti - Classe di Scienze FF.MM.NN., LIII (1). pp. 159-174.

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Abstract

The behaviour of uranyl ion in dimethylsulphoxide, dimethylformamide and acetonitrile has been investigated in the presence of $Cl^—$, $B^r—$, $I^-$ and $CH_3COO^-$ ligands. The investigations were carried out at 25°C by polarography and oscillopolarography. The experimental data allowed the determination of the ratio between the association constants of $U^V^I$ and $U^V$ complexes in DMS0 and DMF. A relative stability sequence of the studied complexes as a function of the “Donor Number” and of "Dieletric Costant” of the solvent has been established.

Item Type: Article
Subjects: M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Fisiche, Matematiche e Naturali > 1973
Depositing User: Dr PP C
Date Deposited: 24 Oct 2012 10:29
Last Modified: 24 Oct 2012 10:29
URI: http://cab.unime.it/mus/id/eprint/1413

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