Messanae Universitas Studiorum

Effetto $trans$ nello stato fondamentale e struttura molecolare del complesso $[Au^I^I^I(PPh_3)Cl_3]$

Bandoli, G. and Cattalini, L. and Clemente, D.A. and Marangoni, G. (1972) Effetto $trans$ nello stato fondamentale e struttura molecolare del complesso $[Au^I^I^I(PPh_3)Cl_3]$. Accademia Peloritana dei Pericolanti Classe FF.MM.NN., 52. pp. 9-12.

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    Abstract

    The molecular structure of triphenylphosphine-trichloro-gold(III) complex is reported. The relatively large Au — Cl distance for the chioride $trans$ to the phosphine ligand and the small but significant deviation from complete planarity are related to the kinetic behaviour of the complex and to the trans labilizing effect in the ligand substitutions at $d^8$ transition metal ions.

    Item Type: Article
    Subjects: M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Fisiche, Matematiche e Naturali > 1972
    M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Giuridiche, Economiche e Politiche > 1972
    Divisions: UNSPECIFIED
    Depositing User: Dr M P
    Date Deposited: 25 Oct 2012 13:28
    Last Modified: 25 Oct 2012 13:28
    URI: http://cab.unime.it/mus/id/eprint/1484

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