Messanae Universitas Studiorum

Studio cinetico della reazione fra isopene e $PdCl_4^2^-$ in metanolo

Pietropaolo, R. and Faraone, F. and Pietropaolo, D. and Piraino, P. (1972) Studio cinetico della reazione fra isopene e $PdCl_4^2^-$ in metanolo. Accademia Peloritana dei Pericolanti Classe FF.MM.NN., 52. pp. 129-139.

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    Abstract

    A kinetic study of the reaction between $PdCl_4^2^-$ and isoprene is reported. The results are interpreted considering the formation, as intermediates, of a $\pi$complex of palladium. (TI) with isoprene, having only one double bond coordinated to the metal, and of a diene chelated compound. By nucleophilic attak of external methanol on the intermediate compounds, the metossi $\pi$allyl complex is obtained.

    Item Type: Article
    Subjects: M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Fisiche, Matematiche e Naturali > 1972
    M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Giuridiche, Economiche e Politiche > 1972
    Divisions: UNSPECIFIED
    Depositing User: Dr M P
    Date Deposited: 26 Oct 2012 12:26
    Last Modified: 26 Oct 2012 12:26
    URI: http://cab.unime.it/mus/id/eprint/1535

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