Studio del meccanismo della reazione tra $PdCl_4 ^2^-$ e 1,3-cicloesadiene in metanolo

Pietropaolo, R. and Rotondo, E. and Faraone, F. and Pietropaolo, D. (1972) Studio del meccanismo della reazione tra $PdCl_4 ^2^-$ e 1,3-cicloesadiene in metanolo. Accademia Peloritana dei Pericolanti Classe FF.MM.NN., 52. pp. 141-149.

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Abstract

A kinetic study of the reaction between $PdCl_4^2^-$ and 1,3-cyclohexadiene is reported. The results are interpreted considering the formation of a $\pi$-complex of palladium (II) with 1,3-cyclohexadiene, having only one double bond coordinated to the metal. By nucleophilic attack of the methanol, on the coordinated olefinic double bond the methoxy $\pi$-aliyl complex is obtained.

Item Type: Article
Subjects: M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Fisiche, Matematiche e Naturali > 1972
M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Giuridiche, Economiche e Politiche > 1972
Depositing User: Dr M P
Date Deposited: 26 Oct 2012 10:46
Last Modified: 26 Oct 2012 10:46
URI: http://cab.unime.it/mus/id/eprint/1537

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