Messanae Universitas Studiorum

Studio del meccanismo della reazione tra $PdCl_4 ^2^-$ e 1,3-cicloesadiene in metanolo

Pietropaolo, R. and Rotondo, E. and Faraone, F. and Pietropaolo, D. (1972) Studio del meccanismo della reazione tra $PdCl_4 ^2^-$ e 1,3-cicloesadiene in metanolo. Accademia Peloritana dei Pericolanti Classe FF.MM.NN., 52. pp. 141-149.

[img]
Preview
PDF
Download (1316Kb) | Preview

    Abstract

    A kinetic study of the reaction between $PdCl_4^2^-$ and 1,3-cyclohexadiene is reported. The results are interpreted considering the formation of a $\pi$-complex of palladium (II) with 1,3-cyclohexadiene, having only one double bond coordinated to the metal. By nucleophilic attack of the methanol, on the coordinated olefinic double bond the methoxy $\pi$-aliyl complex is obtained.

    Item Type: Article
    Subjects: M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Fisiche, Matematiche e Naturali > 1972
    M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Giuridiche, Economiche e Politiche > 1972
    Divisions: UNSPECIFIED
    Depositing User: Dr M P
    Date Deposited: 26 Oct 2012 12:46
    Last Modified: 26 Oct 2012 12:46
    URI: http://cab.unime.it/mus/id/eprint/1537

    Actions (login required)

    View Item