Messanae Universitas Studiorum

Studio del meccanismo di reazione del bis-salicilaldeide Ni (II) con n-butilammina

Marsala, V. and Rotondo, E. and Pietropaolo, R. and Faraone, F. (1972) Studio del meccanismo di reazione del bis-salicilaldeide Ni (II) con n-butilammina. Accademia Peloritana dei Pericolanti Classe FF.MM.NN., 52. pp. 151-157.

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    Abstract

    A kinetic study of the reaction between bis(salycilaldheyde) Ni (Il) and n-butylamine is reported. The resuits are interpreted considering that, in an equilibrium reaction, an adduct between the starting complex and the n-butylamine, bonded to the carbonyl carbon atom, is formed. The migration a hydrogen atom on the oxygen of the car bonyl group and the elimination of water catalyzed by $CH_30^-$ give the final bis-(salycilaldimine) Ni (II) complex.

    Item Type: Article
    Subjects: M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Fisiche, Matematiche e Naturali > 1972
    M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Giuridiche, Economiche e Politiche > 1972
    Divisions: UNSPECIFIED
    Depositing User: Dr M P
    Date Deposited: 26 Oct 2012 12:51
    Last Modified: 26 Oct 2012 12:51
    URI: http://cab.unime.it/mus/id/eprint/1538

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