Faraone, G. and Ricevuto, Vittorio and Romeo, Raffaello and Trozzi, M. (1972) Configurazione dello stato di transizione nelle sostituzioni di leganti coordinati al platino (II). Accademia Peloritana dei Pericolanti Classe FF.MM.NN., 52. pp. 171-181.
The rate of displacernent of $Cl^-$ in $trans$ e $cis$ $[Pt (PEt_3)_2 (R) Cl]$ (R = phenyl, o-tolyl and mesityl) by $CN^-$ has been studied in propan-2 ol water 6% mixture. The analysis of the relative reactivity in the two set of isomers gives some indication about the configuration of the transition state. It is shown that the literature data concerning the reactions of the same systems with pyridine are not suitable. The $trans$ complexes does not undergo the bimolecular attack by pyridine and the $cis$ complexes spontaneously convert into its trans isomers before or during their reaction with pyridine in ethanolic solution.
|Subjects:||M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Fisiche, Matematiche e Naturali > 1972
M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Giuridiche, Economiche e Politiche > 1972
|Depositing User:||Dr M P|
|Date Deposited:||26 Oct 2012 11:22|
|Last Modified:||22 Jan 2013 12:14|
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