Messanae Universitas Studiorum

Proprietà termodinamiche di complessi di ioni attinoidi in soluzione acquosa

Magon, L. and Di Bernardo, P. and Corigliano, F. and Bismondo, A. and Portanova, R. (1974) Proprietà termodinamiche di complessi di ioni attinoidi in soluzione acquosa. Accademia Peloritana dei Pericolanti Classe FF.MM.NN. , 54. pp. 49-55.

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    Abstract

    Enthalpic and entropic contributions to the formation of actinide complexes with different ligands have been evaluated. The literature data are in agreement with an entropic stabilization of the complexes, while the enthalpy term, except in few cases, opposes the complex formation. Both $ \Delta S$ and $ \Delta H$ values decrease with increasing coordination of ligands. Informations bave been gained on the nature of reactions and bonding.

    Item Type: Article
    Subjects: M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Fisiche, Matematiche e Naturali > 1974 (2)
    Divisions: UNSPECIFIED
    Depositing User: Dr M P
    Date Deposited: 30 Oct 2012 13:09
    Last Modified: 30 Oct 2012 13:09
    URI: http://cab.unime.it/mus/id/eprint/1610

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