Magon, L. and Di Bernardo, P. and Corigliano, F. and Bismondo, A. and Portanova, R. (1974) Proprietà termodinamiche di complessi di ioni attinoidi in soluzione acquosa. Accademia Peloritana dei Pericolanti Classe FF.MM.NN. , 54. pp. 49-55.
Enthalpic and entropic contributions to the formation of actinide complexes with different ligands have been evaluated. The literature data are in agreement with an entropic stabilization of the complexes, while the enthalpy term, except in few cases, opposes the complex formation. Both and values decrease with increasing coordination of ligands. Informations bave been gained on the nature of reactions and bonding.
Actions (login required)