Messanae Universitas Studiorum

Studio del meccanismo della reazione del dicloro (1,5-cicloottadiene)palladio(II) con 2,2'-dipiridile

Pietropaolo, R. and Tresoldi, G. and Rotondo, E. and Faraone, F. (1974) Studio del meccanismo della reazione del dicloro (1,5-cicloottadiene)palladio(II) con 2,2'-dipiridile. Accademia Peloritana dei Pericolanti, 54. pp. 133-142.

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    Abstract

    A kinetic study of the reaction between dichloro (1,5-cyclooctadiene) palladium(H) and 2,2’-bipyridyl is reported. The proposed mechanism involves formation of the solvato species [Pd(l,5-COD)Cl(solv)]+, in an equilibrium reaction, followed by slow reaction with bipyridyl to give [Pd(1,5-COD) $(Dipy)]^2^+$. This reacts fast with Cl- giving the final product $Pd(Dipy)Cl_2$.

    Item Type: Article
    Subjects: M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Fisiche, Matematiche e Naturali > 1974 (2)
    Divisions: UNSPECIFIED
    Depositing User: Dr M P
    Date Deposited: 31 Oct 2012 11:24
    Last Modified: 31 Oct 2012 11:24
    URI: http://cab.unime.it/mus/id/eprint/1645

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