Pietropaolo, R. and Tresoldi, G. and Rotondo, E. and Faraone, F. (1974) Studio del meccanismo della reazione del dicloro (1,5-cicloottadiene)palladio(II) con 2,2'-dipiridile. Accademia Peloritana dei Pericolanti, 54. pp. 133-142.
A kinetic study of the reaction between dichloro (1,5-cyclooctadiene) palladium(H) and 2,2’-bipyridyl is reported. The proposed mechanism involves formation of the solvato species [Pd(l,5-COD)Cl(solv)]+, in an equilibrium reaction, followed by slow reaction with bipyridyl to give [Pd(1,5-COD) . This reacts fast with Cl- giving the final product .
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