Messanae Universitas Studiorum

Studio del meccanismo di formazione dei complessi del rame(II) con le basi di Schiff

Pietropaolo, R. and Rotondo, E. and Faraone, F. and Tresoldi, G. (1974) Studio del meccanismo di formazione dei complessi del rame(II) con le basi di Schiff. Accademia Peloritana dei Pericolanti Classe FF.MM.NN., 54. pp. 143-155.

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Abstract

A kinitic study of the reaction between bis-(salicylaldheyde)copper(II) and N-but0amine is reported. Two stages were observed and the inverse dependence, in the first stage, on the methoxide concentration is interpreted considering a competition between $CH_3O^-$ and N-butilamine for an attack-site on the carbonyl carbon atom of the coordinated salicylaldheyde. The different behaviour of bis-(salicyialdheyde)copper(II) and bis-(salicylaldheyde)nickel(II) in the reaction with N-butilamine is also discussed.

Item Type: Article
Subjects: M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Fisiche, Matematiche e Naturali > 1974 (2)
Depositing User: Dr M P
Date Deposited: 31 Oct 2012 10:29
Last Modified: 31 Oct 2012 10:29
URI: http://cab.unime.it/mus/id/eprint/1647

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