Pietropaolo, R. and Rotondo, E. and Faraone, F. and Tresoldi, G. (1974) Studio del meccanismo di formazione dei complessi del rame(II) con le basi di Schiff. Accademia Peloritana dei Pericolanti Classe FF.MM.NN., 54. pp. 143-155.
A kinitic study of the reaction between bis-(salicylaldheyde)copper(II) and N-but0amine is reported. Two stages were observed and the inverse dependence, in the first stage, on the methoxide concentration is interpreted considering a competition between and N-butilamine for an attack-site on the carbonyl carbon atom of the coordinated salicylaldheyde. The different behaviour of bis-(salicyialdheyde)copper(II) and bis-(salicylaldheyde)nickel(II) in the reaction with N-butilamine is also discussed.
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