Messanae Universitas Studiorum

Sintesi, caratterizzazione e struttura del bis[2,6diacetil piridina bis(fenilidrazione)protonato] tetraclorodiossouranio(VI). $CH_3CN$

Graziani, R. and Bombieri, G. and Forsellini, E. and Paolucci, G. (1974) Sintesi, caratterizzazione e struttura del bis[2,6diacetil piridina bis(fenilidrazione)protonato] tetraclorodiossouranio(VI). $CH_3CN$. Accademia Peloritana dei Pericolanti, Classe di Scienze FF. MM. NN., LIV. pp. 177-180.

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    Abstract

    Reaction of 2,6 diacetylpyridine-bis(phenylhydrazone) with commercial uranyl chloride under a variety of different conditions gives complexes of the type $[2LH]^2+[UO_2Cl_4]^2-.xCH_3CN$ (x = 1 or 2). The structure of the title compound has been determined by X ray analysis.
    The $[UO_2C1_4]^2-$ anions have approximately $D_4h$ symmetry with the uranyl group perpendicular to the equatorial plane in which the four chlorine atoms occupy the corners of a square. The organic cations are approximately planar.

    Item Type: Article
    Subjects: M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Fisiche, Matematiche e Naturali > 1974 (2)
    Divisions: UNSPECIFIED
    Depositing User: Dr A F
    Date Deposited: 31 Oct 2012 13:24
    Last Modified: 31 Oct 2012 13:24
    URI: http://cab.unime.it/mus/id/eprint/1675

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