Equilibri di complessazione e di ripartizione nel sistema cobalto II - tiocianato

Corigliano, F. (1974) Equilibri di complessazione e di ripartizione nel sistema cobalto II - tiocianato. Accademia Peloritana dei Pericolanti Classe FF.MM.NN., 54. pp. 257-264.

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Abstract

The cobalt(II)-thiocyanate system has been studied by partition between a 3 $M Na(NCS, ClO_4)$ aqueous solution and methylisobutylketone. The metal phase distribution has been determined radiometrically, by means of cobalt - 60. Values of the formation constants $K_n(n= 1-4)$ and of the partition constant $D_4$ (referred to the $Co(NCS)_4^2^-$ species) have been calculated and refined by a program written in FORTRAN IV for CDC 6600 computer.

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