Bontempelli, G. and Mazzocchin, G. A. and Magno, F. and Seeber, R. (1974) Processi elettrodici di composti ossigenati dell'azoto in acetonitrile. Parte II- Ione nitrito. Accademia Peloritana dei Pericolanti, Classe di Scienze FF. MM. NN., LIV. pp. 213-221.
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Abstract
The electrochemical behaviour of nitrite ions in acetonitrile medium has been investigated at platinum electrodes. The nitrite ion undergoes three consecutive oxidation steps with the formation of NO and $NO_3-$, of $N_2O_4$ and of $NO_2+$ respectively.
A fourth anodic wave, due to the oxidation of $NO_3-$ ions, is also observed but it has been established that $NO_3-$ is formed by hydrolysis of $N_2O_4$ as a consequence of the presence of water, at trace level in acetonitrile solvent.
| Item Type: | Article |
|---|---|
| Subjects: | M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Fisiche, Matematiche e Naturali > 1974 M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Lettere Filosofia e belle Arti > 1974 |
| Depositing User: | Dr A F |
| Date Deposited: | 31 Oct 2012 12:25 |
| Last Modified: | 22 Jan 2013 09:18 |
| URI: | http://cab.unime.it/mus/id/eprint/1696 |
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