Processi elettrodici di composti ossigenati dell'azoto in acetonitrile. Parte II- Ione nitrito

Bontempelli, G. and Mazzocchin, G. A. and Magno, F. and Seeber, R. (1974) Processi elettrodici di composti ossigenati dell'azoto in acetonitrile. Parte II- Ione nitrito. Accademia Peloritana dei Pericolanti, Classe di Scienze FF. MM. NN., LIV. pp. 213-221.

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Abstract

The electrochemical behaviour of nitrite ions in acetonitrile medium has been investigated at platinum electrodes. The nitrite ion undergoes three consecutive oxidation steps with the formation of NO and $NO_3-$, of $N_2O_4$ and of $NO_2+$ respectively. A fourth anodic wave, due to the oxidation of $NO_3-$ ions, is also observed but it has been established that $NO_3-$ is formed by hydrolysis of $N_2O_4$ as a consequence of the presence of water, at trace level in acetonitrile solvent.

Item Type: Article
Subjects: M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Fisiche, Matematiche e Naturali > 1974 (2)
Depositing User: Dr A F
Date Deposited: 31 Oct 2012 12:25
Last Modified: 22 Jan 2013 09:18
URI: http://cab.unime.it/mus/id/eprint/1696

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