Bontempelli, G. and Mazzocchin, G. A. and Magno, F. and Seeber, R. (1974) Processi elettrodici di composti ossigenati dell'azoto in acetonitrile. Parte II- Ione nitrito. Accademia Peloritana dei Pericolanti, Classe di Scienze FF. MM. NN., LIV. pp. 213-221.
atti_3_1974_213.pdf - Submitted Version
The electrochemical behaviour of nitrite ions in acetonitrile medium has been investigated at platinum electrodes. The nitrite ion undergoes three consecutive oxidation steps with the formation of NO and $NO_3-$, of $N_2O_4$ and of $NO_2+$ respectively. A fourth anodic wave, due to the oxidation of $NO_3-$ ions, is also observed but it has been established that $NO_3-$ is formed by hydrolysis of $N_2O_4$ as a consequence of the presence of water, at trace level in acetonitrile solvent.
|Subjects:||M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Fisiche, Matematiche e Naturali > 1974 (2)|
|Depositing User:||Dr A F|
|Date Deposited:||31 Oct 2012 12:25|
|Last Modified:||22 Jan 2013 09:18|
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