Biader Ceipidor, U. and Carunchio, V. (1974) Intermedi dinucleari nella reazione di ossidazione del cobalto(II) in presenza di acido picolinico. Accademia Peloritana dei Pericolanti Classe F.MM.NN. , 54. pp. 331-334.
The oxidation reaction of cobalt(II) with sodium peroxide in aqueous solution in the presence of picolinic acid was investigated by visible spectroscopy. It was possibie to put into evidence two $\mu$ -peroxo bridged species, with complexation ration L/M = 2:2 and 4:2 respectively (T = - 5°C, ionic strenght 1,2M by $NaCl0_4$ and pH 2,40). The conditional concentrations quotients at equilibrium and molar absorptivities were determined using some graphical methods.
|Subjects:||M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Fisiche, Matematiche e Naturali > 1974 (2)|
|Depositing User:||Dr M P|
|Date Deposited:||05 Nov 2012 09:10|
|Last Modified:||05 Nov 2012 09:10|
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