Messanae Universitas Studiorum

Spettri di trasferimento di carica del rutenocene

Sostero, S. and Traverso, O. and Mazzocchin, G. A. (1974) Spettri di trasferimento di carica del rutenocene. Accademia Peloritana dei Pericolanti Classe FF.MM.NN., 54. pp. 367-372.

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    Abstract

    The electronic transition of ruthenocene in halocarbon solvents (RCl) which appears in the 285-300 nm spectral range is attributed to dissociative charge-transfer,

    $C_10H_10Ru + RCl  ^ hv \longrightarrow C_10H_10Ru + Cl-+ R$
    Electron transfer absorption is characteristic of ruthenocene in those halocarbon solvents which have a low half-wave potential. Association constants and molar extinction coefficients for ruthenocene-RC1 $(CCl_4, ClCH_2-CH_2Cl)$ CTTS complexes have been measured.

    Item Type: Article
    Subjects: M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Fisiche, Matematiche e Naturali > 1974 (2)
    Divisions: UNSPECIFIED
    Depositing User: Dr M P
    Date Deposited: 05 Nov 2012 13:19
    Last Modified: 22 Jan 2013 08:51
    URI: http://cab.unime.it/mus/id/eprint/1775

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