Messanae Universitas Studiorum

Spettri di trasferimento di carica del rutenocene

Sostero, S. and Traverso, O. and Mazzocchin, G. A. (1974) Spettri di trasferimento di carica del rutenocene. Accademia Peloritana dei Pericolanti Classe FF.MM.NN., 54. pp. 367-372.

[thumbnail of atti_3_1974_367.pdf] PDF
atti_3_1974_367.pdf
Restricted to users from Unime

Download (1MB) | Request a copy

Abstract

The electronic transition of ruthenocene in halocarbon solvents (RCl) which appears in the 285-300 nm spectral range is attributed to dissociative charge-transfer,

$C_10H_10Ru + RCl ^ hv \longrightarrow C_10H_10Ru + Cl-+ R$
Electron transfer absorption is characteristic of ruthenocene in those halocarbon solvents which have a low half-wave potential. Association constants and molar extinction coefficients for ruthenocene-RC1 $(CCl_4, ClCH_2-CH_2Cl)$ CTTS complexes have been measured.

Item Type: Article
Subjects: M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Fisiche, Matematiche e Naturali > 1974
M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Lettere Filosofia e belle Arti > 1974
Depositing User: Dr M P
Date Deposited: 05 Nov 2012 12:19
Last Modified: 22 Jan 2013 07:51
URI: http://cab.unime.it/mus/id/eprint/1775

Actions (login required)

View Item View Item