Messanae Universitas Studiorum

Proprietà di trasporto elettrico del tiofosfato di ferro intercalato con il litio

Calareso, C. and Currò, G. M. and Grasso, V. and Neri, F. and Silipigni, L. (1994) Proprietà di trasporto elettrico del tiofosfato di ferro intercalato con il litio. Accademia Peloritana dei Pericolanti, Classe di Scienze FF. MM. NN., LXXII (Supplement 1). pp. 359-368.

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    Abstract

    We have carried out $dc$ conductivity measurements on the lithium intercalation complexes $Li_xFePS_3$ both during the intercalation process and after the intercalation was ceased. Prelirninary results for equilibrated samples are presented as a function of both the temperature and the intercalation time. As in the $Li_xNiPS_3$ case, an increase in the electrical conductivity and a contemporary decrease in the activation energy are observed, These features seem to indicate that, with respect to the pure $FePS_3$, a new conduction mechanism takes piace at a different energy levei since the very beginning of the intercaiation process. In the eariy intercalation times, the empirical model, proposed for the $Li_xNiPS_3$ complexes, was used to correlate the data as a function of the intercalation time and as a function of temperature. For the investigated intercalation times a possibie nature of the reduction sites is also provided.

    Item Type: Article
    Subjects: M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Fisiche, Matematiche e Naturali > 1994 > Supplemento 1 parte 2
    M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Medico-Biologiche > 1994 > Supplemento 1 parte 2
    M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Giuridiche, Economiche e Politiche > 1994 > Supplemento 1 parte 2
    M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Lettere, Filosofia e belle Arti > 1994 > Supplemento 1 parte 2
    Divisions: UNSPECIFIED
    Depositing User: Mr Nunzio Femminò
    Date Deposited: 14 Apr 2014 16:59
    Last Modified: 17 Apr 2014 09:42
    URI: http://cab.unime.it/mus/id/eprint/5155

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