Effetto solvente nelle reazioni del trans-[Pt(piperidina)$_2$CI$_2$]CON CI Br. - Indagini radiochimiche e spet-trofotometiche

Faraone, G. and Cattalini, L. and Ricevuto, Vittorio and Romeo, Raffaello and Martelli , M. (2005) Effetto solvente nelle reazioni del trans-[Pt(piperidina)$_2$CI$_2$]CON CI Br. - Indagini radiochimiche e spet-trofotometiche. Accademia Peloritana dei Pericolanti Classe FF. MM. NN. , 83. pp. 19-29.

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Abstract

The kinetics for the substitution ractions of trans-$[pt(piperidin_2CI_2]$ with $Li^3^6 CI$ and $N(C_2H_5)_4Br$ using the solvents:$CH_3OH, C_2H_5OH,$ and $(CH_3)_2CO$ at different temperatures are reported. The kinetics were follwed with radiochemical and spectrofotometrical technique. The reactions occour according with the rate equation: $k_o_b_s=k_1+k_2[Y-]$. The ratio of the specific rates of the second order for the ractions with $Br-$ and $^3^6Cl-, k_2^B^r/k_2^3^6^C^l,$ decreasein the order $CH_3OH> C_2H_5OH> ter-C_4H_9OH,$ that is in the order of increasing the strie factors of the organic radicals. The reactivity of the two studied nucleophiles in $(CH_3)_2CO$ is higler than in the protic solvents.

Item Type:	Article
Subjects:	M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Fisiche, Matematiche e Naturali > 2005 > Supplemento 2 M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Medico-Biologiche > 2005 > Supplemento 2 M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Giuridiche, Economiche e Politiche > 2005 > Supplemento 2 M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Lettere Filosofia e belle Arti > 2005 > Supplemento 2
Depositing User:	Dr M P
Date Deposited:	19 Sep 2012 10:28
Last Modified:	22 Jan 2013 11:59
URI:	http://cab.unime.it/mus/id/eprint/571

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