Messanae Universitas Studiorum

Cinetica di spostamento del gruppo $SnCl_3-$ coordinato al Pt(II)

Faraone, G. and Ricevuto, Vittorio and Romeo, Raffaello and Trozzi, M. (2005) Cinetica di spostamento del gruppo $SnCl_3-$ coordinato al Pt(II). Accademia Peloritana dei Pericolanti Classe FF.MM.NN., 83. pp. 31-40.

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    Abstract

    Nucleophilic substitution reactions of trans- $[Pt(P(C_2H_5)_3)_2(C_6H_5)(SnCl_3)]$ with $SCN-, SeCN-$ and $SC(NH_2)_2,$ in methanol, acetonitrile, dimethylformamide at 30°C, are reported. The results are compared with the literature data concerning the substrate $_t_r_a_n_s-[Pt(P(C_2H_5)_3)_(C_6h_5)Cl].$ The values of specific rate constants $k_1$ and $k_2$ are discussed in terms of a possible fivecoordinate formation as a reaction intermediate state.

    Item Type: Article
    Subjects: M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Fisiche, Matematiche e Naturali > 2005 > Supplemento 2
    M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Medico-Biologiche > 2005 > Supplemento 2
    M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Giuridiche, Economiche e Politiche > 2005 > Supplemento 2
    M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Lettere, Filosofia e belle Arti > 2005 > Supplemento 2
    Divisions: UNSPECIFIED
    Depositing User: Dr M P
    Date Deposited: 19 Sep 2012 11:28
    Last Modified: 22 Jan 2013 12:54
    URI: http://cab.unime.it/mus/id/eprint/579

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