# $\Delta \ H- \Delta \ S$ relationships in complex formation reactions in solution

De Marco, Domenico and Giannetto, Antonino (1994) $\Delta \ H- \Delta \ S$ relationships in complex formation reactions in solution. Accademia Peloritana dei Pericolanti, Classe di Scienze FF. MM. NN., LXXII. pp. 249-272.

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atti_3_1994_249.pdf - Submitted Version

The conditions for the occurrence of linear $\Delta \ H- \Delta \ S( \Delta \ H= \Delta \ Hres+ \tau \Delta \ S)$ relationships are deduced. Models for the interpretation of the parameters $\Delta \ Hres$ and $\Delta \ Sres= \Delta \ Hres/ \tau \$ are proposed. The Enthalpy-Entropy interlay in complex formation reactions for different acceptor-donorinteractions in hard solvents have been analized in critical way.