$\Delta \ H- \Delta \ S$ relationships in complex formation reactions in solution

De Marco, Domenico and Giannetto, Antonino (1994) $\Delta \ H- \Delta \ S$ relationships in complex formation reactions in solution. Accademia Peloritana dei Pericolanti, Classe di Scienze FF. MM. NN., LXXII. pp. 249-272.

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Abstract

The conditions for the occurrence of linear $\Delta \ H- \Delta \ S( \Delta \ H= \Delta \ Hres+ \tau \Delta \ S)$ relationships are deduced.
Models for the interpretation of the parameters $\Delta \ Hres$ and $\Delta \ Sres= \Delta \ Hres/ \tau \$ are proposed.
The Enthalpy-Entropy interlay in complex formation reactions for different acceptor-donorinteractions in hard solvents have been analized in critical way.

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Item Type:	Article
Subjects:	M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Fisiche, Matematiche e Naturali > 1994 M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Medico-Biologiche > 1994 M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Giuridiche, Economiche e Politiche > 1994 M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Lettere Filosofia e belle Arti > 1994
Depositing User:	Dr A F
Date Deposited:	19 Sep 2012 11:42
Last Modified:	19 Sep 2012 11:42
URI:	http://cab.unime.it/mus/id/eprint/687

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