Cencetti, G. and Onori, G. and Santucci, A. Ionic Hydration in aqueous alkali from density and compressibility values. Accademia Peloritana dei Pericolanti Classe FF.MM.NN., 69. pp. 175-193.
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The adiabatic compressibility of aqueous solutions of some alkali halides has been determined as a function of both concentration and temperature. A simple two-state model of solutions which retain the Gurney [Ionic Processes in Solution (Mc Graw-Hill, New York, 1953)] concept of water coordination shells and their overlapping as the salt concentration increases has been employed to interpret the data. The alkali halides examined show a consistent pattern for the size and compressibility of hydration shells as a function of ionic radius.
|Subjects:||M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Fisiche, Matematiche e Naturali > 1991 > Supplemento 1|
M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Scienze Giuridiche, Economiche e Politiche > 1991 > Supplemento 1
M.U.S. - Miscellanea > Atti Accademia Peloritana > Classe di Lettere, Filosofia e belle Arti > 1991 > Supplemento 1
|Depositing User:||Dr M P|
|Date Deposited:||01 Oct 2012 13:10|
|Last Modified:||01 Oct 2012 13:10|
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